Roman Chemical Energy Storage Project

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6 Frequently Asked Questions about “Roman Chemical Energy Storage Project”

What is thermo-chemical energy storage?

The thermo-chemical energy storage is based on utilization of heat of reaction of reversible chemical reactions. For example a chemical compound of type BA can be split reversibly into the components A and B via adding heat. In this process the added quantity of heat RH ∋ is being converted into the chemical energy of the systems A and B .

What is thermal energy storage based on reversible chemical reactions?

Thermal energy storage based on gas–solid reversible chemical reactions offers higher-energy storage densities than commercially implemented sensible heat-storage systems. Despite the promise, it is a much less mature technology, and several aspects still require further improvement.

Are thermo-chemical storages a potential for solar thermal heating systems?

4. Conclusion The presented research activities and results show that thermo-chemical storages have a great potential for solar thermal heating systems. The high storage density and the low heat losses over a long duration are leading to high solar fraction with comparatively moderate sizes of storage and collector area.

What is thermal energy storage based on redox reactions?

Thermal energy storage based on redox reactions follows the general formula described in Equation  (1) Here, in the first step, the oxide is reduced (normally at high temperatures, Tred > 500 °C) to an oxide with lower valence, process in which lattice oxygen is released.

What is a simplified reactor model of thermo-chemical heat storage?

Derived from the detailed numerical analysis a simplified reactor model of the thermo-chemical heat storage was developed for TRNSYS and implemented. The substantial properties and the characteristics of the reaction, which the model is based on, correlate to these of calcium chloride (CaCl 2 ) and zeolite.

How is metal oxide stored in a solar reactor?

The reduced metal oxide is stored in a hot tank until transferred to the oxidation reactor, where the discharge step (heat release) takes place. The reoxidized material is then stored in an additional cold tank until transferred again to the directly irradiated solar reactor.

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